It takes a minimum of three legs to build a stool, and a minimum of three logs to build a good fire.
A BD daughter recently learned this basic Boy Scout fact after failing to start holiday fires. It requires a tent of wood to hold in enough heat to produce and ignite the heated gasses which create the rapid oxidation we call a flame. The flame is the burning gasses. The complex and mysterious chemistry of ignition is the key to flame.
The gasses, of course, are hydrocarbons. Wood is nothing but unripened oil or pre-coal. I explained to her (she does not seem to have a chemistry brain yet) that slow oxidation is called "rotting," slightly quicker oxygenation is called "smoldering," quick oxidation is called "fire," and extremely quick oxidation is called "explosion."
Medium controlled oxidation is called "life," and why we exhale CO2 (hydrocarbons + oxygen = mostly CO2 + H20 + heat/energy), and why we are above room temperature most of the time. It's an exothermic chemical reaction. We animals are masterfully designed to control and harness these chemistries in our bodies.